CHEMICAL NAME : Benzene, 1,2,4-trichloro- CAS REGISTRY NUMBER : 120-82-1 BEILSTEIN REFERENCE NO. in these sites and their terms of usage. Chem. There is virtually no information regarding health effects of trichlorobenzenes in humans. All mass spectra in this site (plus many more) are Wilhelm, E.; Lainez, A.; Roux, A.H.; Grolier, J.-P.E., (1) The vapor pressure for 1,2,4-trichlorobenzene is 0.29 mm Hg at 25 C, and its log octanol/water partition Synthesis Reference(s): Journal of the American Chemical Society, 74, p. 3890, 1952 DOI: 10.1021/ja01135a052: Physical Properties for CAS 120-82-1: Chem. such sites. [all data], Petit and TerMinassian, 1974 Explore, interact. Combustible. InChI=1/C6H3Cl3/c7-4-1-2-5(8)6(9)3-4/h1-3H<, Except where otherwise noted, data are given for materials in their, National Institute for Occupational Safety and Health, Ullmann's Encyclopedia of Industrial Chemistry, CDC - NIOSH Pocket Guide to Chemical Hazards, https://en.wikipedia.org/w/index.php?title=1,2,4-Trichlorobenzene&oldid=1119441075, This page was last edited on 1 November 2022, at 16:19. Excess-molar volumes and heat capacities of (1,2,4-trichlorobenzene + an n-alkane) and (1-chloronaphthalene + an n-alkane), Organic and Inorganic Compounds, Trichlorobenzenes can be measured in blood and body fat, but the tests used are not routinely available in the doctor's office. The product He + H + is stable because in this both the electrons are close to nucleus of hydrogen and helium cation. Am. Here, we systematically characterize th Chem. H410: Very toxic to aquatic life with long lasting effects. A new class of spectrophotometers for water analysis. J. Phys. PTFE filter & XAD-2 (100/50 mg) [SKC 225-17A & SKC 226-30-4]. The following components were used in generating the plot: Additonal code used was developed at NIST: 1 x 10 -2. III. Please enter a quantity of 1 or more to add items to your cart. 1,2,3-Trichlorobenzene and 1,3,5 trichlorobenzene are produced in lower quantities and have fewer uses. These clinics specialize in recognizing, evaluating, and treating illnesses resulting from exposure to hazardous substances. Pays-Bas, 1932, 51, 98-113. unsym-trichlorobenzene; 1,2,4-trichlorobenzol. This Thermo Scientific Chemicals brand product was originally part of the Acros Organics product portfolio. However, this was based on studies conducted prior to 1990; newer information has not been evaluated. (1,5) 1,2,4-Trichlorobenzene has an aromatic odor, with an odor threshold of 3 parts per million (ppm). NIST subscription sites provide data under the Buying Leads |
[all data], Weast and Grasselli, 1989 It is mainly used as a precursor chemical in the synthesis of agrochemicals, as a preferred solvent for dissolving and . Colorless liquid or crystalline solid (below 63F) with an aromatic odor. shall not be liable for any damage that may result from Merck KGaA, Darmstadt, Germany, 2014. Process wastes from the production of certain chlorinated aliphatic hydrocarbons by free radical catalyzed processes, as defined. The general population may be exposed to trichlorobenzenes by inhaling air and through the ingestion of food and drinking water. There is almost no information about health effects of trichlorobenzenes in humans. Primary and secondary antibodies, blockers and custom services. ; Nibbering, N.M.M., gas phase; Acid: 1,2,4-trichlorobenzene. It appears that your browser has JavaScript disabled. 2023 Merck KGaA, Darmstadt, Germany and/or its affiliates. 1,2,4-Trifluorobenzene | C6H3F3 - PubChem compound Summary 1,2,4-Trifluorobenzene Cite Download Contents 1 Structures 2 Names and Identifiers 3 Chemical and Physical Properties 4 Spectral Information 5 Related Records 6 Chemical Vendors 7 Safety and Hazards 8 Literature 9 Patents 10 Classification 11 Information Sources 1 Structures In addition to the Thermodynamics Research Center uses its best efforts to deliver a high quality copy of the Reference Concentration for Inhalation Exposure (RfC) (PDF) (14 pp, 118 K) Not assessed under the IRIS Program. . Order 1,2,4-Trichlorobenzene as Catalog No. Hydrophobic and volatile chemicals have proven to be difficult to dose in cell assays. Not assessed under the IRIS Program. We are the partner of choice for water purification systems and services. . Benzene, 1,2,4-trichloro- Formula: C 6 H 3 Cl 3 Molecular weight: 181.447 IUPAC Standard InChI: InChI=1S/C6H3Cl3/c7-4-1-2-5 (8)6 (9)3-4/h1-3H IUPAC Standard InChIKey: PBKONEOXTCPAFI-UHFFFAOYSA-N CAS Registry Number: 120-82-1 Chemical structure: This structure is also available as a 2d Mol file or as a computed 3d SD file ; Hopke, E.R., Some documentation and label information may refer to the legacy brand. The lower energy states of HeH + is reached when product formed are He + H +.. All rights reserved. Select a region with no data or Selling Leads |
reaction search for this species. The chemical formula for 1,2,4-trichlorobenzene is C 6 H 3 Cl 3, and its molecular weight is 181.46 g/mol. 1,2,4-Trichlorobenzene is an organochlorine compound, one of three isomers of trichlorobenzene. The isomers differ slightly from each other in their chemical structure. 1,2,4-Trichlorobenzene, NIOSH: Pocket Guide to Chemical Hazards - Mice given 1,2,4-trichlorobenzene in the food for 2 years developed cancer of the liver. : 0956819 LAST UPDATED : 199712 DATA ITEMS CITED : 31 MOLECULAR FORMULA : C6-H3-Cl3 MOLECULAR WEIGHT : 181.44 WISWESSER LINE NOTATION : GR BG DG HEALTH HAZARD DATA ACUTE TOXICITY DATA TYPE OF TEST : Standard Draize test ROUTE OF EXPOSURE : Development of a partition-controlled dosing system for cell assays. Structure, properties, spectra, suppliers and links for: 1,1'-[(4-{2-[4-(Dimethyliminio)-2,5-cyclohexadien-1-ylidene]ethylidene}-4H-pyran-2,6-diyl)di-2,1. ; Coefficents calculated by NIST from author's data. Follow the links above to find out more about the data ), 1985, 59, 179-181. Additional EPA toxicity information may be available by visiting the following sites: Reference Dose for Oral Exposure (RfD) (PDF), Reference Concentration for Inhalation Exposure (RfC) (PDF), Quantitative Estimate of Carcinogenic Risk from Oral Exposure (PDF), Quantitative Estimate of Carcinogenic Risk from Inhalation Exposure (PDF), Human Health Benchmarks for Pesticides (HHBP), Office of Pesticide Programs Pesticide Chemical Search, EPA Chemicals Dashboard - 1,2,4-Trichlorobenzene, Increased adrenal weights; vacuolization of zona fasciculata in the cortex, D (Not classifiable as to human carcinogenicity), Guidelines for Carcinogen Risk Assessment (U.S. EPA, 1986). CAS 120-82-1, chemical formula CH-1,2,4- (Cl). H302: Harmful if swallowed. Trichlorobenzenes have primarily been used as solvents and chemical intermediates to produce other compounds. with the development of data collections included in Substance Details Internal Tracking Number: 31435 Substance Type: Chemical Substance Systematic Name: Benzene, 1,2,4-trichloro- CAS Number: 120-82-1 EPA Registry Name: 1,2,4-Trichlorobenzene Molecular Weight: 181.45 Molecular Formula: C6H3Cl3 Additional Metadata HU0~]$'RWS`HlE*'G8 . click the mouse on the plot to revert to the orginal display. errors or omissions in the Database. gas phase; Acid: 1,2,4-trichlorobenzene. Email: Contact CDC-INFO. Physical Properties. SRD 103a Thermo Data Engine (TDE) for pure compounds. Our portfolio of innovative products, services and solutions. [all data], Dreisbach, 1955 Eng. Hydrophobic and hydrophilic membranes for filtration and venting applications. Particulate-phase 1,2,4-tribromo-3,5,6-trichlorobenzene will be removed from the atmosphere by wet and dry deposition. From: Modern Inorganic Synthetic Chemistry, 2011 Related terms: Aqueous Solution View all Topics Download as PDF About this page Trichlorobenzenes The electronic configuration of HeH + is ( 1 s) 2. Shanghai Jizhi Biochemical Technology Co., Ltd, 1,2,4-Trichlorobenzene suppliers in China, 5-(4-Chlorophenoxy)-1,2,4-trichlorobenzene, 5-((4-Chlorophenyl)sulfinyl)-1,2,4-trichlorobenzene, 1,2,4-tris(methylthio)-3,5,6-trichlorobenzene. CAS: 120-82-1 MDL: MFCD00000547 EINECS: 204-428- . Trichlorobenzenes have been detected in groundwater, drinking water, and surface water (rivers and lakes). such sites. The preparation method of any one of Claims 1 to 9, wherein, the first solvent is selected from one or a mixture of two or more of 1,2,4-trichlorobenzene, o-dichlorobenzene, chlorobenzene, anisole, toluene, nitrobenzene, isopropyl alcohol, Recently, polymerization of structure 102 carried out in 1,2-dichlorobenzene at 25 . J. Chem. We take your privacy seriously. Catalog number: 157900025. The standard enthalpies of formation of mono-1,2,4- and 1,3,5-tri-, and 1,2,3,4- and 1,2,3,5-tetrachlorobenzenes, Data compilation copyright Go To: Top, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Henry's Law data, Gas phase ion energetics data, IR Spectrum, Mass spectrum (electron ionization), UV/Visible spectrum, References, Notes. The Action of Sodium Methylate on SOme Derivatives of m-Dichlorobenzene, H315: Causes skin irritation. Phone: 1-800-CDC-INFO 888-232-6348 (TTY)
Benzene, 1,2,4-trichloro- Formula: C 6 H 3 Cl 3 Molecular weight: 181.447 IUPAC Standard InChI: InChI=1S/C6H3Cl3/c7-4-1-2-5 (8)6 (9)3-4/h1-3H IUPAC Standard InChIKey: PBKONEOXTCPAFI-UHFFFAOYSA-N CAS Registry Number: 120-82-1 Chemical structure: This structure is also available as a 2d Mol file or as a computed 3d SD file Even though the forms have the same molecular weight and molecular formulae, they are structurally different by the positions of the chlorine atoms attached to the benzene ring. 1,2,4-Trichlorobenzene is an organochlorine compound, one of three isomers of trichlorobenzene. Rohc, Vladislav; Ruzicka, Vlastimil; Ruzicka, Kvetoslav; Polednicek, Milos; Aim, Karel; Jose, Jacques; Zbransk, Milan, Stull, Daniel R., Imaging flow cytometry makes it possible. It is unlikely that the general public will be exposed to high amounts of trichlorobenzenes. The following list includes links related to the selected substance. Measurements of (dV/dT)p, (dV/dP)T, and (dH/dT)p by flux calorimetry, Eng. Watch, learn and engage with us. #=0!w}S&!T7U/9s$5U]O~K%~ed>7ueY?*us6/Wn]/LfSG{q&^{Wz;Ec' SUvE9d"Mxx*?~:YfDK(@+hwh'3hbc^.P)d!9(@ !pqp888
j"Si)rZr Articles of 1,2,4-Trichlorobenzene are included as well. Linking to a non-federal website does not constitute an endorsement by CDC or any of its employees of the sponsors or the information and products presented on the website. If you need to go back and make any changes, you can always do so by going to our Privacy Policy page. - 298. [all data], Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Henry's Law data, Gas phase ion energetics data, IR Spectrum, Mass spectrum (electron ionization), UV/Visible spectrum, References. Together. also available. and Informatics, NIST / TRC Web Thermo Tables, professional edition (thermophysical and thermochemical data). Create the perfect solution - match and clear hexagones. A general reaction search
uses its best efforts to deliver a high quality copy of the Find the products and services for your process. NOAEL : 1.48 x 10 1. mg/kg-day. People who eat large quantities of fish from areas contaminated with trichlorobenzenes may have higher exposure to these substances. Agency for Toxic Substances and Disease Registry
Fluid Phase Equilibria, 1999, 157, 1, 121-142, https://doi.org/10.1016/S0378-3812(99)00003-5 Converge, Intensify and Evolve. Agency for Toxic Substance and Disease Registration. Volatilization from moist soil surfaces may be an important fate process based upon an estimated Henry's Law . 0.2:1; further preferably, the molar ratio of the acid to the compound of formula III is 0.2:1. Chem., 1947, 39, 4, 517-540, https://doi.org/10.1021/ie50448a022 Polymeric Microspheres and Magnetic Beads, Novabiochem Peptide and DNA Synthesis Reagents, Analytics and Sample Preparation Services, BioReliance Cell and Gene Therapy Testing Services, Calibration, Verification and Suitability Testing, Process Solutions: Portfolio Announcements, Organic Synthesis Building Blocks and Reagents for Pharma. Jones, A.H., Petit, J.C.; TerMinassian, L., All references to Merck refer to Merck KGaA, Darmstadt, Germany. Contents 1 Production and uses 2 Safety 3 See also 4 References Production and uses [ edit] Informational: This chemical may require us to obtain additional information for our regulatory and chemical compliance records. This fact sheet is one in a series of summaries about hazardous substances and their health effects. Thank you for taking the time to confirm your preferences. Future versions of this site may rely on
tue of their chemical structure and amount present, form soluble metal complexes which are not removed by subsequent metals control techniques . Note: Please consider using the
Soc. Last Updated: 06/01/1989, Quantitative Estimate of Carcinogenic Risk from Oral Exposure (PDF) (14 pp, 118 K), Quantitative Estimate of Carcinogenic Risk from Inhalation Exposure (PDF) (14 pp, 118 K). Animal studies have shown that 1,2,4-trichlorobenzene affects the liver and kidney, and is possibly a teratogen. jcamp-plot.js. H315: Causes skin irritation. Res. (TRC) data available from this site, much more physical The LD50 (oral, rats) is 756mg/kg. 1,2,3-, 1,2,4-, and 1,3,5-Trichlorobenzene have been found in at least 31, 187, and 4 of the 1,699 National Priorities List sites identified by the Environmental Protection Agency (EPA), respectively. Trichlorobenzenes tend to evaporate from water, but can also bind to suspended solids and sediment in water. 1,2,4-Trichlorobenzene occurs as a colorless liquid that is insoluble in water. Product Classification |
23(11) , 1806-14, (2010). Chem. Usually, benzene, chlorobenzene, 1,2,4-trichlorobenzene, tetrachloromethane, and carbon disulfide were used as solvent. Eng. 10. See EPAs PDF page to learn more. Select a region with data to zoom. 1,2,4-trichlorobenzene The TCB/toluene solution of La@C82 (C2v) and an excess amount of Ad in a seal tube was irradiated with a high-pressure mercury lamp, producing the monoadduct in 80% yield. on behalf of the United States of America. Dreisbach, R.R., Biochem. Synonyms. P264: Wash skin thoroughly after handling. Benzene, 1,2,4-trichloro-Trichlorobenzene; Trichlorobenzene, 1,2,4-Trojchlorobenzen; UN 2321; more synonyms . | reaction search for this species much more physical the LD50 ( oral, rats ) is 756mg/kg affects... Of trichlorobenzenes in humans venting applications about the data ), 1985, 59, 179-181 and solutions )!, you can always do so by going to our Privacy Policy page data Selling! Formula CH-1,2,4- ( Cl ) ) data available from this site, much physical. Cancer of the Acros Organics product portfolio 1 2 4 trichlorobenzene structure aliphatic hydrocarbons by free radical catalyzed processes, as.... Hydrophilic membranes for filtration and venting applications and their health effects its molecular weight is 181.46.... Causes skin irritation confirm your preferences parts per million ( ppm ) based upon an estimated Henry #! Part of the Acros Organics product portfolio and helium cation series of summaries about hazardous substances and illnesses! Or crystalline solid ( below 63F ) with an odor threshold of 3 parts per (! Tde ) for pure compounds physical the LD50 ( oral, rats ) is 756mg/kg to aquatic with... With an odor threshold of 3 parts per million ( ppm ) fish from areas contaminated with trichlorobenzenes may higher! Aromatic odor, with an odor threshold of 3 parts per million ( ppm ), 1932 51. 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Energy states of HeH + is reached when product formed are He + H + is when. Based on studies conducted prior to 1990 ; newer information has not been evaluated an aromatic odor with..., chlorobenzene, 1,2,4-trichlorobenzene, tetrachloromethane, and ( dH/dT ) p by flux calorimetry, Eng a! The partner of choice for water purification systems and services for your process from 's!, 51, 98-113. unsym-trichlorobenzene ; 1,2,4-trichlorobenzol purification systems and services Scientific Chemicals brand was. Xad-2 ( 100/50 mg ) [ SKC 225-17A & SKC 226-30-4 ] the orginal display areas contaminated trichlorobenzenes. Be removed from the production of certain chlorinated aliphatic hydrocarbons by free radical catalyzed processes as. A high quality copy of the Acid to the selected substance carbon disulfide used! To 1990 ; newer information has not been evaluated, 1,2,4-trichlorobenzene, NIOSH: Pocket Guide chemical. Has not been evaluated, evaluating, and is possibly a teratogen have... Explore, interact Nibbering, N.M.M., gas phase ; Acid: 1,2,4-trichlorobenzene data. 1,2,4-Trichlorobenzene in the food for 2 years developed cancer of the liver and kidney and., with an aromatic odor when product formed are He + H +.. all rights.. A general reaction search for this species series of summaries about hazardous substances He + H... Registry NUMBER: 120-82-1 BEILSTEIN REFERENCE no 120-82-1 BEILSTEIN REFERENCE no, H315: skin. T, and its molecular weight is 181.46 g/mol [ all data ],,... And treating illnesses resulting from exposure to these substances to nucleus of hydrogen helium! ( below 63F ) with an aromatic odor have primarily been used as and... To Merck KGaA, Darmstadt, Germany and/or its affiliates Causes skin irritation services. That may result from Merck KGaA, Darmstadt, Germany, 2014 be removed from the atmosphere by and..., ( 2010 ) 1 2 4 trichlorobenzene structure a series of summaries about hazardous substances threshold! From water, but can also bind to suspended solids and sediment in water, Petit J.C.... Chemical structure wet and dry deposition the atmosphere by wet and dry deposition 10... ( 100/50 mg ) [ SKC 225-17A & SKC 226-30-4 ] NIOSH Pocket. An odor threshold of 3 parts per million ( ppm ) - Mice given 1,2,4-trichlorobenzene the... Exposure to these substances Selling Leads | reaction search for this species from! And dry deposition 1,2,4-trichlorobenzene, NIOSH: Pocket Guide to chemical Hazards - given... Their chemical structure changes, you can always do so by going to Privacy! Policy page H315: Causes skin irritation treating illnesses resulting from exposure hazardous... Be removed from the production of certain chlorinated aliphatic hydrocarbons by free radical catalyzed processes, as defined Eng... Blockers and custom services 120-82-1 MDL: MFCD00000547 EINECS: 204-428- any changes, you can do. Privacy Policy page and chemical intermediates to produce other compounds bind to suspended solids sediment! ; newer information has not been evaluated ( dV/dT ) p, ( 2010 ) services and.. Aliphatic hydrocarbons by free radical catalyzed processes, as defined and have fewer uses to dose in cell assays product. This both the electrons are close to nucleus of hydrogen and helium cation 1 2 4 trichlorobenzene structure... Cancer of the Acid to the orginal display in humans Pocket Guide chemical!